Last April 17, twelve brave guinea pigs (non-specialists and mostly non-scientists) came to my home in Hamilton NJ to learn.
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This forum is the story of our journey.
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My fascination is that the quantum properties of electrons, whose causative factors emerged in seconds after big bang, result in chemical bonding. It’s neat and beautiful: can I get others to understand, and myself to understand it better, so we can discuss it? In other words, my theme is that the basic structure of the universe results, ultimately, in molecules.
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OUR FIRST MEETING
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One look at ‘TheOfficial Meeting Outline’ for April 17 and you would see: it was too ambitious. In one session: the big bang, three of the four forces, Heisenberg’s Uncertainty Principle, Schrodinger’s equation, orbitals, the periodic table! What was I thinking! My hands were shaking. I’d prepared this ambitious outline because I was afraid that if I didn’t MAKE PROGRESS, people wouldn’t see the magical story that I see. But unfortunately, it was too much. People were lost by the time I’d finished. My first meeting was not the success I’d hoped.
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So, let’s think of that meeting as an introduction the topics I want to cover, and I willwalk through what the group did. At least, most of my guests agreed to come back!
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7:00 PM:
We settled down to coffee and snacks while I spent a few minutes on the Scientific Method, with emphasis, I hope, on the human side: the triumph and the controversies. Also: people got to know each other: the artist and budding writer, the philosopher (my colleague at Rutgers, Jeff Buechner) the animal rescue enthusiast, the corporate executive, the environmental activist who efforts have preserved an important fossil reef, the author (Jennifer Morgan).
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7:12: Next: MATTER.
Protons, neutrons, electrons. I used a worksheet to describe how small these particle are: (see attached). A brief mention of the strong a weak nuclear force, and it is time to build nuclei!
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7:15: We used plastic Easter eggs for protons and wads of duct tape for neutrons. Neutrons, I say, are ‘nuclear glue’. My homily regarding strong and weak forces and quantum spin properties is completely lost amid the groans and yelps. The Easter eggs and duct tape wads don’t stick together well! The nuclei keep falling apart! but quick: an opportunity. The universe was well into its formation before the larger nuclei were formed, after all. It’s not easy to put nuclei together. The unwieldy bundles of too many Easter eggs (protons) and too few duct tape wads (neutrons) are ‘unstable nuclei’ read: radioactive nuclei.
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Now, some group members spontaneously collaborate to make larger bundles by combining small ones. On their own they have discovered FUSION (the combining of smaller nuclei)—which happens during stellar nucleosynthesis. Finally, we counted the Easter eggs in our largest bundle: 13. It was aluminum.
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I go the periodic table (taped to my dining room cabinet) to explain how we organize the elements. We find aluminum. We find atoms corresponding to the smaller wads, boron, nitrogen. We find carbon. We try to imagine the wad that would be gold, or uranium (the largest nuclei that is found in nature, I explain.) Progress. Some understanding. We drink coffee.
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7:20 I am half way through my time, and the main theme is yet to come: Electrons. I used grapes for electrons. Time to add the grapes to our aluminum to complete our atom!
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7:23 I explain charge and electromagnetic force. (We play with magnets, quickly quickly. At least, no one is yawning.) The grapes (electrons) will be attracted to the Easter Egg wads (protons). Where will they go?
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7:25: I explain that nature seeks the lowest energy level. Therefore, I ask, should we attach our grapes to the surface of the nucleus and let them lazily sit? No! Heisenberg’s uncertainty principle (I explain it quickly, including the formula and the mention of Plank’s constant) tells us that we cannot know position and speed of tiny particles like electrons. ‘Stopped’ doesn’t work. Electrons must always move.
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So, let’s have our grapes skim right on or above the surface. No! They have to have allowed an energy state. I try to explain allowed energy state. This goes poorly, partly because my own understanding is not complete.
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7:28: I have purchased a little trick flashlight and now I shine it through two slits. It’s partly an artifact, but I get an interference pattern. The guests seem to like this and make their own interference pattern. Electrons, too, are waves, I say, and would make an interference pattern if we sent them through two slits. I show De Broglie’s equation (Planks constant again!) Electrons are both waves and particles. I give everyone wavelengths cut from glitter paper. There is no time to make standing waves, as I’d planned, so I have my guests create circular ‘orbits’ around imaginary nuclei. How many ‘wavelengths’ do we use? This is a visualization, an analogy, for an allowed state—see, I ask, how some circles are possible, others aren’t? Let’s count the wavelengths. It’s an integer, correct? Well, that will be our ‘quantum number’. We can describe our ‘allowed circles’ with ‘quantum numbers’. Some seems to get it, some are baffled. That’s okay. Proceed.
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7:35: I explain: we have to use quantum theory to see where to put the electrons. I introduce Schrodinger’s equation. I rip through an explanation of equations: You put information in, you get a solution out. How many cakes do you have if you bake two a day and you bake three days? Total cakes equal (two a day) times (three days), y = 2x. Voila, an equation. Equations have variables and operations, I say. Schrodinger’s equation is like that, I say, only fantastically harder, and it has more variables. I show the equation, a quick explanation of the terms, and wish I have more time to explain its history and importance.
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7:38: I say things like this:
Schrodinger’s equation is a wave equation. It is a postulate. No one completely understand why it works.
It contains variables about the electrons and their states
It requires complex mathematical operations that take years of study to understand
It has three quantum numbers that constrain the allowed states
It contains an imaginary number i. This causes the ‘solutions’, ‘output’, to be divided into phases that can be opposite to one another and change in complicated ways.
It can’t be solved. The equation could not be solved with any known mathematics.So can we know where the electron is?
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7:40: Yes, I say. We can square the wavefunction. Squaring imaginary numbers makes them usable. Scientists obtain solutions telling where the electrons are, but only probabilities, not certainties.
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Some guests have glazed eyes. Time for more activity with our Easter eggs and grapes!
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7:42: I show them a simple s orbital, a solution to Schrodinger’s equation. It is described by three quantum numbers. (Remember our analogy, I say.) Let’s put our grapes in this orbital, I say. (All 13 grapes—it’s aluminum, remember?) Putting all our grapes in the lowest energy orbital would be best, correct? No! Egads, we are not done yet, and I have to explain spin. I do my best. Electrons are Fermions and cannot have an identical particle with the same energy state. I explain about the Fermions needing to turn around twice to get back to the beginning. I do a little trick with a glass on my palm. The grapes can’t all go in the same orbital.
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7:46: So we need more orbitals, because we have 13 grapes. So we enter more variables and more allowed energies in our equation and make more solutions, all the time higher in energy and farther from the nucleus. The allowed energy states, the ‘orbitals’, I say, are like an upside down skyscraper, like an upside down Taipei 101. As we go out, each ‘story’ each ‘floor’, becomes farther from the nucleus and more complex. This means, I say, that atoms are mostly empty space. I show them p, d, f orbitals (taped to my walls.)
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I suggest we put in one grape per orbital. Correct? NO! We put two in each orbital. This is because electrons have two spins states. Now each electron has unique and different quantum numbers, as required because they are fermions.
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7:50: I need to wrap this up. I can see the bafflement. It is best just to quit. Carbon, I say, has four orbitals (‘four apartments’) in the ‘second story’. It is four electrons away from being filled, from having full occupancy. I point dramatically to the periodic table, count four to the end of the second shell. Calculations, I say, show that ‘filled occupancy’ is more stable. Voila! Carbon needs to make four bonds. I point to a picture showing the structure of diamond. I hold up a marshmallow with four toothpicks, and attach more marshmallows and more toothpicks. Carbon is unique and amazing. It makes four bonds. From it, DNA is made. I am done.
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The guests each got a chance to talk next. They are neat and special people and we had a fun discussion. We agreed that we need to meet again. We agree we need to discuss ‘quantum properties’ and for fun, quantum weirdness. I will try to explain spin state better, wave particle duality, and the thing with the glass in the palm of my hand. Jeff Buechner will give a brief talk on the logic of spin states. We will drop marbles into a tank of water, blow across the tops of beer bottles, make more allowed states with our glitter wavelengths. We will talk of ‘spooky action at a distance’ and multiverses.
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The next meeting is May 8. Stay tuned.
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